sc::molecularhessian(3)

NAME

sc::MolecularHessian - MolecularHessian is an abstract class that computes a molecule's second derivatives of the energy with respect to changes in the nuclear coordinates.

SYNOPSIS

#include <hess.h>
Inherits sc::SavableState.
Inherited by sc::DiagMolecularHessian, sc::FinDispMolecularHessian,
sc::GuessMolecularHessian, and sc::ReadMolecularHessian.
Public Member Functions
MolecularHessian (const Ref< KeyVal > &)
    The MolecularHessian KeyVal constructor is used to generate a
    MolecularHessian derivative object from the input.
MolecularHessian (StateIn &)
void save_data_state (StateOut &)
    Save the base classes (with save_data_state) and the members in the
    same order that the StateIn CTOR initializes them.
RefSCDimension d3natom ()
Ref< SCMatrixKit > matrixkit () const
virtual RefSymmSCMatrix cartesian_hessian ()=0
    Return the cartesian hessian.
virtual void set_energy (const Ref< MolecularEnergy > &energy)
    Some MolecularHessian specializations require a molecular energy
    object.
virtual MolecularEnergy * energy () const
    This returns a MolecularEnergy object, if used by this
    specialization.
Static Public Member Functions
static RefSCMatrix cartesian_to_symmetry (const Ref< Molecule > &m,
    Ref< PointGroup > pg=0, Ref< SCMatrixKit > kit=0)
    Find transformation matrix from cartesian to symmetry coordinates.
static void write_cartesian_hessian (const char *filename, const Ref<
    Molecule > &m, const RefSymmSCMatrix &hess)
    Write the hessian in a simple text format.
static void read_cartesian_hessian (const char *filename, const Ref<
    Molecule > &m, const RefSymmSCMatrix &hess)
    Read the hessian from a simple text format.
Protected Attributes
Ref< Molecule > mol_
RefSCDimension d3natom_
Ref< SCMatrixKit > matrixkit_

Detailed Description

MolecularHessian is an abstract class that computes a molecule's second derivatives of the energy with respect to changes in the nuclear
coordinates.

Constructor & Destructor Documentation

sc::MolecularHessian::MolecularHessian (const Ref< KeyVal > &)
The MolecularHessian KeyVal constructor is used to generate a MolecularHessian derivative object from the input.
It reads the keywords below.
KeywordTypeDefaultDescription moleculeMoleculenoneThe Molecule object.

Member Function Documentation

void sc::MolecularHessian::save_data_state (StateOut &) [virtual]
Save the base classes (with save_data_state) and the members in the
same order that the StateIn CTOR initializes them.
This must be implemented by the derived class if the class has data.
Reimplemented from sc::SavableState.
Reimplemented in sc::FinDispMolecularHessian, sc::ReadMolecularHessian, sc::GuessMolecularHessian, and sc::DiagMolecularHessian.
virtual void sc::MolecularHessian::set_energy (const Ref< MolecularEnergy >
& energy) [virtual]
Some MolecularHessian specializations require a molecular energy object.
The default implementations of this ignores the argument.
Reimplemented in sc::FinDispMolecularHessian.
virtual MolecularEnergy* sc::MolecularHessian::energy () const [virtual]
This returns a MolecularEnergy object, if used by this specialization.
Otherwise null is returned.
Reimplemented in sc::FinDispMolecularHessian.
static RefSCMatrix sc::MolecularHessian::cartesian_to_symmetry (const Ref<
Molecule > & m, Ref< PointGroup > pg = 0, Ref< SCMatrixKit > kit = 0) [static]
Find transformation matrix from cartesian to symmetry coordinates.

Author

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